364002
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364002
Aldrich
(1S,2S)-(−)-1,2-Diphenylethylenediamine
97%
| Synonym: | (1S,2S)-(−)-1,2-Diamino-1,2-diphenylethane |
| CAS Number: | 29841-69-8 |
| Linear Formula: | [C6H5CH(NH2)-]2 |
| Molecular Weight: | 212.29 |
| Beilstein Registry Number: | 3201645 |
| MDL number: | MFCD00082751 |
| PubChem Substance ID: | 24862409 |
Description
| Application | Versatile ligand for the formation of metal complexes.1 Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis.2 |
| Packaging | 100, 500 mg in glass btl |
Properties
| assay | 97% |
| optical activity | [α]20/D −102°, c = 1 in ethanol |
| optical purity | ee: 98% (GLC) |
| mp | 83-85 °C(lit.) |
Safety
| Personal Protective Equipment | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
References
| Cited Reference | 1. Mukaiyama, T. Aldrichimica Acta 29, 59, (1996) |
| 2. Chenier, P.J. et al. Tetrahedron Lett. 38, 7341, (1997) | |
| Beilstein | Beil. 13,III,473 |
| Fieser | Fieser 16,153 / Fieser 17,127 |
| reference | FT-NMR 1 (2), 574:A / RegBook 1 (1), 1467:M / Structure Index 1, 229:D:5 |
